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Which Vet did you go see? I usually inject Baytril for URI.
I have had to give Baytril orally. There are a few ways that I have done it, but it all depends on your cham and his/her demeanor. If they instinctively gape at you when you get near it, just squirt it in (although be sure not to squirt it so hard that it goes down its throat). I have also grabbed the cham from behind like you said, but also you can tap them (gently) on the nose and they will (most times) instictively gape at you.
Another way to try is to inject the liquid into a juicy feeder worm, such as a horn worm, butter worm or silk worm, and give them the worm. Kills 2 birds with one stone that way.
Some notes from a recent talk on antibiotic usage in exotics by Dr. Doug Mader from the FL Keys:
Baytril injectable is to be given as a single IM (intramuscular) injection or IV only. Then, it is to be followed up with the tablets or a liquid suspension orally. This is on the label and for a good reason. The injectable may be given safely orally as well. Baytril is rapidly and well-absorbed through the GIT. Baytril has a pH of 11.0, which is almost as basic as bleach. It is VERY corrosive and damaging to body tissues when injected IM. Multiple injections can cause tissue necrosis and sterile abscesses (tissue death without infection).
Baytril is NOT the only drug that may be used safely in exotics and is widely abused and overprescribed. Vets often turn their brains off when seeing exotics and immediately Rx Baytril for everything.