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it wouldnt be scenting with an air freshener, just rubbing your hands/neck on vines and leaves so that they smell like you. If the animal grows up surrrounded by your scent, it will be very comfortable with you... Very true for animals that use scent as a main sense. Obviously, chams use sight, but i was wondering if their sense of smell was good enough to try doing something like this.
What the scent itself is isn't the only aspect to consider. Scent marking would be most meaningful to social species that consider the presence of other individuals a good thing. Chams are solitary. Intruders are intruders, not friends. Now some chams touch their tongues to traveling branches possibly to pick up the scent of another cham that may have used the same branch, but it isn't because they are hoping for company! Some species may use scent marking (rubbing their vents on branches they use all the time) to lay out the boundaries of their territories...its a type of warning to others, not an invitation.
IMHO putting scents on your cham's branches or plants would most likely mean nothing to him or might even be confusing or alarming. You won't really know the effect and it might not be welcome. I would not bother. If you want to socialize with your cham your visual behavior will work better. They are more likely to react to a color you wear, not a smell.
And of course this does not include phermones that are not really odors.
Now that you have brought up this point, then would a free range used by one chameleon earlier cause stress if it was used by another chameleon at a separate time? Would they detect the scent of the first chameleon and think there was an intruder?
I haven't noticed that every cham tests branches for another cham's scent. SOME seem to but others don't seem to care. I'm certain they come across other cham scents in their wild territories. I'd suspect that once each of them is familiar with the scent of the other in their shared free range it isn't going to stress them out horribly. Maybe all the message ends up saying is "I'm one of two chams who walk on this branch" and that's the end of it.
My melleri shared a free range for years and they tolerated each other once they got to know each other.
Mine have never seemed to have any problems using the same free ranges. I've only really ever seen panthers lick branches and then some don't even do it.