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IMHO it looks more like a bruise to me then a burn. Has he been rubbing his eye?
If it were a burn, I would expect the top of his head right above that eye to be burned too. It doesn't look like a burn either. Every now and then one of my panthers will get a random discolored spot like that, and it will go away. Not sure what they are but it doesn't seem to have any effect on them.